Investigations of iron-alumina metal-ceramic composites: effect of ruthenium and nickel on the hydrogen reduction of trivalent iron during the formation of the composite

Verelst, M. ; Kannan, K. R. ; Subbanna, G. N. ; Rao, C. N. R. ; Brieu, M. ; Rousset, A. (1993) Investigations of iron-alumina metal-ceramic composites: effect of ruthenium and nickel on the hydrogen reduction of trivalent iron during the formation of the composite Materials Research Bulletin, 28 (4). pp. 293-303. ISSN 0025-5408

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002554...

Related URL: http://dx.doi.org/10.1016/0025-5408(93)90061-H

Abstract

Effect of ruthenium and nickel on the reduction behavior of Fe3+/Al2O3 to give the Fe1bAl2O3 metal-ceramic composite has been studied by employing X-ray diffraction. 57Fe Mössbauer spectroscopy and electron microscopy. Both ruthenium and nickel promote the hydrogen reduction of Fe3+, giving nearly total reduction to the metallic phase at 1220K. Besides metallic iron in the ferromagnetic α-form, paramagnetic alloys of Fe with Ru and Ni are formed during the reduction.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Iron; Alumina; Composites
ID Code:42226
Deposited On:02 Jun 2011 06:56
Last Modified:02 Jun 2011 06:56

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