An open-framework cobalt oxalato-squarate containing a ligated amine

Dan, Meenakshi ; Rao, C. N. R. (2003) An open-framework cobalt oxalato-squarate containing a ligated amine Solid State Sciences, 5 (4). pp. 615-520. ISSN 1293-2558

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S12932...

Related URL: http://dx.doi.org/10.1016/S1293-2558(03)00047-5

Abstract

A cobalt oxalato-squarate of the formula [Co2(C4O4)(C2O4)(C3N2H4)2], containing a ligated amine has been synthesized hydrothermally and its structure determined by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic space group P21212 with a=18.3845(8) Å, b=5.7884(3) Å, c=7.2598(4) Å, V=772.56(7) Å3 and Z=4. It has a layered structure where two-dimensional sheets are formed by the connectivity of the squarate and the oxalate units with the cobalt centres, with the ligating amine molecules protruding out from the layers.

Item Type:Article
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ID Code:42203
Deposited On:02 Jun 2011 07:39
Last Modified:02 Jun 2011 07:39

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