Szczëśniak, M. M. ; Ratajczak, H. ; Agarwal, Umesh P. ; Rao, C. N. R. (1976) Studies on the lithium bond Chemical Physics Letters, 44 (3). pp. 465-467. ISSN 0009-2614
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Official URL: http://dx.doi.org/10.1016/0009-2614(76)80705-1
Related URL: http://dx.doi.org/10.1016/0009-2614(76)80705-1
Abstract
Semi-empirical and ab initio calculations on 1:1 NH3---lithium halide complexes show that the lithium bond is stronger than the hydrogen bonds formed by the corresponding hydrogen halides. There is an elongation of the Li-halogen bond and a decrease in the stretching force constant in the complex. Unlike in hydrogen bonds, there is an increase in charge on the bridging atom in lithium bonds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 42170 |
| Deposited On: | 02 Jun 2011 05:56 |
| Last Modified: | 02 Jun 2011 05:56 |
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