Stereocontrolled construction of angularly functionalized trans-fused cycloheptanoids via α-hydroxycyclobutane rearrangement followed by retroaldol cleavage

Ranu, Brindaban C. ; Basu, Manas K. (1991) Stereocontrolled construction of angularly functionalized trans-fused cycloheptanoids via α-hydroxycyclobutane rearrangement followed by retroaldol cleavage Tetrahedron Letters, 32 (33). pp. 4177-4178. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)79897-2

Abstract

Acid-catalysed rearrangement of α-hyroxycyclobutane derivatives 3a-3c followed by retroaldol cleavage and oxidation in an one-pot operation furnished angularly carboxylated trans-fused cycloheptanoid compounds 5a-5c.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Trans-fused Cycloheptanoids; Angular Functionalization; Cyclobutane Rearrangement
ID Code:42160
Deposited On:02 Jun 2011 05:40
Last Modified:02 Jun 2011 05:40

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