Reduction of trihalomethyl carbinols and their acetates, mesylates and tosylates by indium metal

Ranu, Brindaban C. ; Samanta, Sampak ; Das, Arijit (2002) Reduction of trihalomethyl carbinols and their acetates, mesylates and tosylates by indium metal Tetrahedron Letters, 43 (34). pp. 5993-5995. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(02)01262-5

Abstract

A study of reduction of trihalomethyl carbinols and their derivatives by indium metal shows that while trichloromethyl carbinols produce a mixture of the corresponding dichloromethyl carbinol and vinylidene dichloride, the acetates, mesylates and tosylates of the trichloro- and tribromomethyl carbinols undergo clean reduction to provide the respective vinylidene dichloride only.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Indium Metal; Reduction; Trihalomethyl Carbinols and Derivatives; Vinylidene Dichloride
ID Code:42155
Deposited On:02 Jun 2011 05:38
Last Modified:02 Jun 2011 05:38

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