Covalent functionalization of metal oxide and carbon nanostructures with polyoctasilsesquioxane (POSS) and their incorporation in polymer composites

Gomathi, A. ; Gopalakrishnan, K. ; Rao, C. N. R. (2010) Covalent functionalization of metal oxide and carbon nanostructures with polyoctasilsesquioxane (POSS) and their incorporation in polymer composites Materials Research Bulletin, 45 (12). pp. 1894-1898. ISSN 0025-5408

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00255...

Related URL: http://dx.doi.org/10.1016/j.materresbull.2010.09.001

Abstract

Polyoctasilsesquioxane (POSS) has been employed to covalently functionalize nanostructures of TiO2, ZnO and Fe2O3 as well as carbon nanotubes, nanodiamond and graphene to enable their dispersion in polar solvents. Covalent functionalization of these nanostructures with POSS has been established by electron microscopy, EDAX analysis and infrared spectroscopy. On heating the POSS-functionalized nanostructures, silica-coated nanostructures are obtained. POSS-functionalized nanoparticles of TiO2, Fe2O3 and graphite were utilized to prepare polymer-nanostructure composites based on PVA and nylon-6,6.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:A. Nanostructures; B. Chemical Synthesis; C. Electron Microscopy
ID Code:41932
Deposited On:31 May 2011 13:33
Last Modified:31 May 2011 13:33

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