Photoelectron spectra of substituted benzenes

Egdell, R. ; Green, J. C. ; Rao, C. N. R. (1975) Photoelectron spectra of substituted benzenes Chemical Physics Letters, 33 (3). pp. 600-607. ISSN 0009-2614

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Photoelectron spectra of several substituted dimethylanilines, nitrobenzenes, acetophenones and nitrosobenzenes have been studied with a view to examine the electronic effects of substituents on the various φ and n levels. The results are discussed in the light of molecular orbital calculations and electronic absorption spectra. Correlation of substituent effects on the IE's with π-electron densities and Hammett substituent constants has enabled rationalization of all available data on mono- and disubstituted benzenes. The IE's generally increase with the electron-withdrawing power of the substituents.

Item Type:Article
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Deposited On:31 May 2011 12:50
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