Pes study of spin-state transitions in d6 transition metal complexes and oxides

Vasudevan, S. ; Vasan, H. N. ; Rao, C. N. R. (1979) Pes study of spin-state transitions in d6 transition metal complexes and oxides Chemical Physics Letters, 65 (3). pp. 444-451. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...

Related URL: http://dx.doi.org/:10.1016/0009-2614(79)80268-7

Abstract

Transitions from the low-to the high-spin state in Fe2+ and Co3+ compounds have been examined by X-ray and UV photoelectron spectroscopy. It has been shown that the core-level bands in XPES, in particular the metal 3s band, as well as the valence bands, are diagnosis in the study of spin-state transitions.

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