Spectroscopic studies of the donor properties of triphenyl-amine, -phosphine, -arsine and -stibine interaction with iodine and phenol

Bhaskar, K. R. ; Bhat, S. N. ; Singh, Surjit ; Rao, C. N. R. (1966) Spectroscopic studies of the donor properties of triphenyl-amine, -phosphine, -arsine and -stibine interaction with iodine and phenol Journal of Inorganic and Nuclear Chemistry, 28 (9). pp. 1915-1925. ISSN 0022-1902

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Official URL: http://dx.doi.org/10.1016/0022-1902(66)80281-6

Related URL: http://dx.doi.org/10.1016/0022-1902(66)80281-6

Abstract

The interaction of iodine with triphenylamine, triphenylphosphine, triphenylarsine and triphenystibine has been investigated by electronic spectroscopy. Transformation of the outer charge-transfer complexes to the inner complexes (quarternary salts) has been examined. The relations of the ionization potentials of the donors with the hvc.t have been discussed and various c.t. parameters have been estimated. Hydrogen bonding of these donors with phenol have been reported.

Item Type:Article
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Deposited On:31 May 2011 12:27
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