Ranu, Brindaban C. ; Mandal, Tanmay (2006) An indium–TMSCl promoted reaction of diphenyl diselenides and aldehydes: novel routes to selenoacetals and alkyl phenyl selenides Tetrahedron Letters, 47 (32). pp. 5677-5680. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.06.012
Abstract
The reaction of diphenyl diselenides with aldehydes in the presence of In-TMSCl has been investigated. Aliphatic aldehydes provide the corresponding selenoacetals, whereas aromatic aldehydes lead predominantly to alkyl phenyl selenides under the same reaction conditions. This constitutes a new approach for the synthesis of selenoacetals and selenides from aldehydes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Selenoacetal; Selenides; Indium; Trimethylsilyl Chloride; Aldehydes |
| ID Code: | 41701 |
| Deposited On: | 31 May 2011 04:53 |
| Last Modified: | 31 May 2011 04:53 |
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