Construction of bicyclo[2.2.2]octanone systems by microwave-assisted solid phase Michael addition followed by Al2O3-mediated intramolecular aldolisation. An eco-friendly approach

Ranu, Brindaban C. ; Guchhait, Sankar K. ; Ghosh, Keya ; Patra, Amarendra (2000) Construction of bicyclo[2.2.2]octanone systems by microwave-assisted solid phase Michael addition followed by Al2O3-mediated intramolecular aldolisation. An eco-friendly approach Green Chemistry, 2 (1). pp. 5-6. ISSN 1463-9262

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2000...

Related URL: http://dx.doi.org/10.1039/A907689A

Abstract

Microwave irradiation of a mixture of cyclohexenones and ethyl acetoacetate adsorbed on the surface of solid lithium S-(-)-prolinate which is then placed on a column of basic alumina leads to the stereoselective construction of bicyclo[2.2.2]octanone systems through Michael addition and subsequent intramolecular aldolisation.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:41513
Deposited On:30 May 2011 05:12
Last Modified:17 May 2016 23:12

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