Use of indium hydride (Cl2InH) for chemoselective reduction of the carbon---carbon double bond in conjugated alkenes

Ranu, Brindaban C. ; Samanta, Sampak (2002) Use of indium hydride (Cl2InH) for chemoselective reduction of the carbon---carbon double bond in conjugated alkenes Tetrahedron Letters, 43 (41). pp. 7405-7407. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(02)01668-4

Abstract

Indium hydride (Cl2InH) generated in situ from a combination of a catalytic amount of indium(III) chloride and sodium borohydride selectively reduces the carbon---carbon double bond in conjugated alkenes such as α, α -dicyano olefins, α, β -unsaturated nitriles, cyano esters, cyanophosphonate, diesters and ketones.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Indium Chloride; Sodium Borohydride; Reduction; Conjugated Alkene; C=C Bond
ID Code:41463
Deposited On:30 May 2011 05:14
Last Modified:30 May 2011 05:14

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