Ranu, Brindaban C. ; Saha, Amit ; Banerjee, Subhash (2008) Catalysis by ionic liquids: significant rate acceleration with the use of [pmIm]Br in the three-component synthesis of dithio-carbamates European Journal of Organic Chemistry, 2008 (3). pp. 519-523. ISSN 1434-193X
Full text not available from this repository.
Official URL: http://onlinelibrary.wiley.com/doi/10.1002/ejoc.20...
Related URL: http://dx.doi.org/10.1002/ejoc.200700842
Abstract
An easily accessible neutral ionic liquid, 1-methyl-3-pentylimidazolium bromide, promoted a one-pot three-component condensation of an amine, carbon disulfide, and an activated alkene/dichloromethane/epoxide to produce the corresponding dithiocarbamates in high yields at room temperature. The reactions are very fast in ionic liquids relative to those in other reaction media. These reactions do not require any additional catalyst or solvent. The ionic liquid can be recovered and recycled for subsequent reactions. A plausible mechanism is suggested.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Ionic Liquids; Dithiocarbamates; Multicomponent Reactions; Catalysis; Rate Acceleration |
| ID Code: | 41461 |
| Deposited On: | 30 May 2011 05:32 |
| Last Modified: | 30 May 2011 05:32 |
Repository Staff Only: item control page
