Adak, Laksmikanta ; Chattopadhyay, Kalicharan ; Ranu, Brindaban C. (2009) Palladium nanoparticle-catalyzed C-N bond formation. A highly regio- and stereoselective allylic amination by allyl acetates The Journal of Organic Chemistry, 74 (10). pp. 3982-3985. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo9003037
Related URL: http://dx.doi.org/10.1021/jo9003037
Abstract
Palladium nanoparticles, generated in situ from the reaction of palladium(II) chloride, have been demonstrated to be an efficient catalyst for C-N bond formation. A variety of aliphatic and aromatic amines have been allylated by substituted and unsubstituted allyl acetates in high yields by using palladium nanoparticles in the presence of a base without any ligand. The allylations are highly regio- and stereoselective.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 41431 |
| Deposited On: | 30 May 2011 05:34 |
| Last Modified: | 30 May 2011 05:34 |
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