Self-assembly of tripodal squaraines: cation-assisted expression of molecular chirality and change from spherical to helical morphology

Ajayaghosh, Ayyappanpillai ; Chithra, Parayalil ; Varghese, Reji (2006) Self-assembly of tripodal squaraines: cation-assisted expression of molecular chirality and change from spherical to helical morphology Angewandte Chemie International Edition, 46 (1-2). pp. 230-233. ISSN 1433-7851

Full text not available from this repository.

Official URL: http://www3.interscience.wiley.com/journal/1134662...

Related URL: http://dx.doi.org/10.1002/anie.200603611

Abstract

Let's do the twist: Tripodal squaraines self-assemble from acetonitrile to form hollow spheres, the complexation of which with Ca2+ or Mg2+ results in extended networks. An analogous chiral dye exhibits a bisignate CD couplet and a helical morphology upon Ca2+ binding (see figure). Thus, the molecular chirality of a functional dye is expressed through specific cation binding and manifested in the form of supramolecular helicity.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Circular Dichroism; Helical Structures; Self-assembly; Squaraine Dyes; Supramolecular Chemistry
ID Code:409
Deposited On:21 Sep 2010 04:39
Last Modified:31 Dec 2010 09:14

Repository Staff Only: item control page