Local modes of substitutional transition metal ions in II-VI semiconductors

Mayur, A. J. ; Dean Sciacca, M. ; Miotkowski, I. ; La Rocca, G. C. ; Ramdas, A. K. ; Rodriguez, S. (1994) Local modes of substitutional transition metal ions in II-VI semiconductors Solid State Communications, 91 (10). pp. 785-789. ISSN 0038-1098

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/003810...

Related URL: http://dx.doi.org/10.1016/0038-1098(94)90648-3

Abstract

The 3d transition metal ions (TMI) substituting for the cations in the tetrahedrally coordinated zincblende II-VI semiconductors display a localized mode above the rest-strahlen when introduced in dilute concentrations. The local mode observed in the infrared exhibits a characteristic dependence on the isotopic mass of the TMI. In the wurtzite II-VIs, the local mode undergoes a splitting into two components, one polarized along the optic axis and the other normal to it. The local mode frequency shows a striking non-monotonic dependence on the number of 3d electrons of the TMI.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:A. Semiconductors; C. Impurities In Semiconductors; D. Phonons; E. Light Absorption And Reflection
ID Code:40430
Deposited On:24 May 2011 14:29
Last Modified:24 May 2011 14:29

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