Rao, C. N. R. ; Bandekar, J. (1978) Analogy between pressure effects and solvent effects on the i.r. spectra of molecules Spectrochimica Acta Part A: Molecular Spectroscopy, 34 (5). pp. 545-547. ISSN 0584-8539
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/058485...
Related URL: http://dx.doi.org/10.1016/0584-8539(78)80052-X
Abstract
Pressure-induced shifts of vibrational frequencies have been correlated in terms of Buckingham's theory of solvent effects on i.r. spectra. It is pointed out that both pressure- and solvent-induced frequency shifts essentially arise from the reorganization of solvent molecules around the solute cavity without significantly affecting the cavity radius.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 40097 |
| Deposited On: | 21 May 2011 08:49 |
| Last Modified: | 21 May 2011 08:49 |
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