Evolution of three-dimensional character across the Lan+1NinO3n+1 homologous series with increase in n

Mohan Ram, R. A. ; Ganapathi, L. ; Ganguly, P. ; Rao, C. N. R. (1986) Evolution of three-dimensional character across the Lan+1NinO3n+1 homologous series with increase in n Journal of Solid State Chemistry, 63 (2). pp. 139-147. ISSN 0022-4596

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002245...

Related URL: http://dx.doi.org/10.1016/0022-4596(86)90163-5

Abstract

Electrical and magnetic properties of La3Ni2O7 and La4Ni3O10 have been investigated in comparison with those of La2NiO4, LaNiO3, and LaSrNiO4. The results suggest an increasing 3-dimensional character across the homologous series Lan+1NinO3n+1 with increase in n. Accordingly, the electrical resistivity decreases in the order La3Ni2O7, La4Ni3O10, and LaNiO3 and this trend is suggested to be related to the percolation threshold. Magnetic properties of these oxides also show some interesting trends across the series.

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