Infrared spectrum and configurations of methyl N-methylthiocarbamate

Chaturvedi, G. C. ; Rao, C. N. R. (1971) Infrared spectrum and configurations of methyl N-methylthiocarbamate Spectrochimica Acta Part A: Molecular Spectroscopy, 27 (1). pp. 65-72. ISSN 0584-8539

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/058485...

Related URL: http://dx.doi.org/10.1016/0584-8539(71)80006-5

Abstract

Normal vibration analysis of the in-plane vibrations of methyl N-methylthiocarbamate, CH3NH(CS)OCH3, has been carried out employing the Urey-Bradley-Shimanouchi force field; the band assignments and force constants have been compared with those of related molecules. Rotational isomerism about the C-N bond of alkylthiocarbamates has been examined by infrared and NMR spectroscopy. Perturbations of the infrared bands of CH3NH(CS)OCH3 in its complexes with iodine and metals have been briefly discussed.

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