Murugesan, Thangamuthu ; Sarode, Prabhakar R. ; Gopalakrishnan, Jagannatha ; Ramachandra Rao, C. N. (1980) A study of copper compounds by X-ray absorption spectroscopy Journal of the Chemical Society, Dalton Transactions (5). pp. 837-839. ISSN 0300-9246
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1980...
Related URL: http://dx.doi.org/10.1039/DT9800000837
Abstract
Chemical shifts, ΔE, of the K-absorption discontinuity in several compounds of copper possessing formal oxidation states between 0 and III have been measured. The shifts show a parabolic dependence on the formal oxidation state as well as on the effective atomic charge, q, on copper. Anomalous chemical shifts shown by some of the compounds are discussed in terms of the bonding in these compounds. The ΔE values have also been correlated with the core electron binding energies obtained from X-ray photoelectron spectroscopy.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 40069 |
| Deposited On: | 21 May 2011 08:01 |
| Last Modified: | 26 May 2011 11:19 |
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