He(I) photoelectron studies of C-nitroso compounds

Egdell, Russell ; Green, Jennifer C. ; Ramachandra Rao, C. N. ; Gowenlock, Brian G. ; Pfab, Josef (1976) He(I) photoelectron studies of C-nitroso compounds Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 72 . pp. 988-995. ISSN 0300-9238

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Official URL: http://pubs.rsc.org/en/content/articlelanding/1976...

Related URL: http://dx.doi.org/10.1039/F29767200988


PES bands due to ionization from n, n and π orbitals of the NO group in some aliphatic nitroso compounds have been identified. In nitrosobenzene derivatives only the n(NO) band can be assigned unequivocally. Substituent effects on the ionization energies in aliphatic and aromatic nitroso compounds have been correlated with substituent constants.

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