Choudhury, Amitava ; Udaya Kumar, D. ; Rao, C. N. R. (2002) Three-dimensional organically templated open-framework transition metal selenites Angewandte Chemie International Edition, 41 (1). pp. 158-161. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...
Related URL: http://dx.doi.org/10.1002/1521-3773(20020104)41:1<158::AID-ANIE158>3.0.CO;2-#
Abstract
One dimensional channels are formed in the three-dimensional open-framework iron selenite [C4N2H12]0.5[Fe2F3(SeO3 )2] (I), which was synthesized hydrothermally from FeCl3·6H2O, HF, and SeO2 in the presence of the organic amine piperazine. The same inorganic framework was also obtained with the amines diethylenetetramine, 1,3-diaminopropane, and ethylenediamine. Compound I displays unusual magnetic frustration behavior that is attributed to the tetrahedral geometry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Crystal Growth; Iron; Magnetic Properties; Mesoporous Materials; Selenium |
| ID Code: | 39991 |
| Deposited On: | 20 May 2011 13:13 |
| Last Modified: | 20 May 2011 13:13 |
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