Orientational phase transitions in C70: a Raman spectroscopic investigation

Chandrabhas, N. ; Jayaram, K. ; Muthu, D. V. S. ; Sood, A. K. ; Seshadri, Ram ; Rao, C. N. R. (1993) Orientational phase transitions in C70: a Raman spectroscopic investigation Physical Review B: Condensed Matter and Materials Physics, 47 (16). pp. 10963-10966. ISSN 1098-0121

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Official URL: http://prb.aps.org/abstract/PRB/v47/i16/p10963_1

Related URL: http://dx.doi.org/10.1103/PhysRevB.47.10963

Abstract

Raman investigations of C70 films in the 14–370-K range show significant changes across the orientational phase transitions around 270 and 330 K. Seven of the Raman modes of C70 soften smoothly across the transitions, the magnitude of the decrease in frequencies being in the range of 2-5 cm−1. Linewidths of the bands increase in the transition region over and above the anharmonic contributions.

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