Vibrational phase relaxation of O-H stretch in bulk water: role of large amplitude angular jumps and negative cross-correlations among the forces on the O-H bond

Abstract

The ultrafast vibrational phase relaxation of O-H stretch in bulk water is investigated in molecular dynamics simulations. The dephasing time (T₂) of the O-H stretch in bulk water calculated from the frequency fluctuation time correlation function (C(t)) is in the range of 70-80 femtosecond (fs), which is comparable to the characteristic timescale obtained from the vibrational echo peak shift measurements using infrared photon echo [W.P. de Boeij, M.S. Pshenichnikov, D.A. Wiersma, Ann. Rev. Phys. Chem. 49 (1998) 99]. The ultrafast decay of C_ω(t) is found to be responsible for the ultrashort T₂ in bulk water. Careful analysis reveals the following two interesting reasons for the ultrafast decay of C_ω(t). (A) The large amplitude angular jumps of water molecules (within 30-40 fs time duration) provide a large scale contribution to the mean square vibrational frequency fluctuation and gives rise to the rapid spectral diffusion on 100 fs time scale. (B) The projected force, due to all the atoms of the solvent molecules on the oxygen (F_O(t)) and hydrogen (F_H(t)) atom of the O-H bond exhibit a large negative cross-correlation (NCC). We further find that this NCC is partly responsible for a weak, non-Arrhenius temperature dependence of the dephasing rate.