TiCl4 catalyzed tandem construction of C-C and C-O bonds: a simple and one-pot atom-economical stereoselective synthesis of spiro-oxindoles

Basavaiah, Deevi ; Rao, Jamjanam Srivardhana ; Reddy, Raju Jannapu ; Rao, Anumolu Jaganmohan (2005) TiCl4 catalyzed tandem construction of C-C and C-O bonds: a simple and one-pot atom-economical stereoselective synthesis of spiro-oxindoles Chemical Communications . pp. 2621-2623. ISSN 1359-7345

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Related URL: http://dx.doi.org/10.1039/b500224a

Abstract

An atom-economical stereoselective synthesis of [{1-acetyl- 5-methyl-6,8-dioxabicyclo(3.2.1) octane}-7-spiro-3'- (indolin-2'-one)] derivatives, containing both the oxindole and 6,8-dioxabicyclo(3.2.1)octanemoieties via TiCl4 catalyzed coupling of 2-acetyl-6-methyl-2,3-dihydro-4H-pyran with isatin derivatives is described.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:3966
Deposited On:13 Oct 2010 07:08
Last Modified:16 May 2016 14:39

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