The Baylis-Hillman adducts as valuable source for one-pot multi-step synthesis: a facile synthesis of substituted piperidin-2-ones

Basavaiah, Deevi ; Reddy, Raju Jannapu ; Lenin, Dandamudi V. (2010) The Baylis-Hillman adducts as valuable source for one-pot multi-step synthesis: a facile synthesis of substituted piperidin-2-ones Helvetica Chimica Acta, 93 (6). pp. 1180-1186. ISSN 0018-019X

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Official URL: http://www3.interscience.wiley.com/journal/1235257...

Related URL: http://dx.doi.org/10.1002/hlca.200900352

Abstract

A facile, convenient, and one-pot multi-step synthesis of substituted piperidin-2-ones from the Baylis-Hillman alcohols derived from various aldehydes and acrylonitrile, involving Johnson-Claisen rearrangement, reduction of an α, β-unsaturated nitrile moiety into the saturated amine-skeleton, followed by cyclization, in an operationally simple procedure, is described.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Baylis-Hillman Adducts; Piperidin-2-ones; Multicomponent Reactions; Johnson-claisen Rearrangement; X-Ray Crystallography
ID Code:3965
Deposited On:13 Oct 2010 07:09
Last Modified:17 Jan 2011 04:05

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