Thio-claisen rearrangement on pyroglutamates

Jain, Sanjay ; Sinha, Neelima ; Dikshit, Dinesh K. ; Anand, Nitya (1995) Thio-claisen rearrangement on pyroglutamates Tetrahedron Letters, 36 (46). pp. 8467-8468. ISSN 0040-4039

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S-allyl/propargyl/methallyl thioimminium salts derived from methyl 1-benzyl-5-thioxoprolinate (1) undergoes a facile thio-Claisen rearrangement which provides an easy access to 4-substituted thioxoprolinates (2-4).

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Deposited On:18 Oct 2010 09:22
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