Basavaiah, Deevi ; Reddy, Ravi Mallikarjuna (2001) Baylis-Hillman chemistry: a convenient stereoselective synthesis of (Z,Z)- and (E,E)-1,4-diallylpiperazines Journal of Chemical Research, 2001 (9). pp. 354-355. ISSN 0308-2342
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Official URL: http://www.ingentaconnect.com/content/stl/jcr/2001...
Related URL: http://dx.doi.org/10.3184/030823401103170250
Abstract
Treatment of piperazine with 3-acetoxy-2-methylenealkanenitriles provides exclusively (1,4)-bis[(2Z)-2-cyanoalk-2-en-1-yl]piperazines. A similar reaction of methyl 3-acetoxy-3-aryl-2-methylenepropanoates with piperazine produces (1,4)-bis[(2E)-3-aryl-2-methoxycarbonylprop-2-en-1-yl]piperazines as the major products.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to In House Publishing. |
| Keywords: | Baylis-Hillman Chemistry; Stereoselectivity; Bisallylamines; Piperazine |
| ID Code: | 3925 |
| Deposited On: | 18 Oct 2010 09:25 |
| Last Modified: | 18 Oct 2010 09:25 |
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