Novel titanium(IV) chloride catalyzed olefination of aldehydes: a simple and convenient synthesis of trans-cinnamic acids

Basavaiah, Deevi ; Rao, Anumolu Jaganmohan (2002) Novel titanium(IV) chloride catalyzed olefination of aldehydes: a simple and convenient synthesis of trans-cinnamic acids Synthetic Communications, 32 (2). pp. 195-201. ISSN 0039-7911

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Related URL: http://dx.doi.org/10.1081/SCC-120002002

Abstract

A variety of aromatic aldehydes were stereoselectively transformed into (E)-cinnamic acids via the reaction with ethyl bromoacetate and triphenylphosphine in the presence of catalytic amount of titanium tetrachloride, followed by hydrolysis and crystallization.

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ID Code:3920
Deposited On:18 Oct 2010 09:26
Last Modified:16 May 2016 14:37

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