Deuterium isotope effect on hydrogen bonding

Singh, Surjit ; Rao, C. N. R. (1966) Deuterium isotope effect on hydrogen bonding Canadian Journal of Chemistry, 44 (22). pp. 2611-2615. ISSN 0008-4042

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The interaction of phenol and phenol-d with a number of donors of varying basicity has been studied in terms of the equilibrium constants, ΔS0, ΔH0, ΔνOH, and ΔνOD and various aspects of deuterium isotope effects on hydrogen bonding have been discussed. The deuterium isotope effects are found to vary markedly with the basicity of the donor and the results are discussed in terms of the zero point contributions to the KH/KD.

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Source:Copyright of this article belongs to NRC Research Press.
ID Code:39173
Deposited On:09 May 2011 10:10
Last Modified:17 May 2016 21:43

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