The first synthesis and determination of absolute stereochemistry of clonostachydiol- Part II

Rama Rao, A. V. ; Murthy , V. S. ; Sharma, G. V. M (1995) The first synthesis and determination of absolute stereochemistry of clonostachydiol- Part II Tetrahedron Letters, 36 (1). pp. 143-146. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...

Related URL: http://dx.doi.org/10.1016/0040-4039(94)02196-I

Abstract

The first total synthesis of clonostachydiol has been achieved from two appropriately protected hydroxy acids that are derived from (D)-xylose and 1,2-O-isopropylidene (D)-glyceraldehyde. This synthesis has proved the absolute configuration of four stereocenters in clonostachydiol as 2R,3S,8R,11R unambiguously.

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