Synthesis of (±) Fredericamycin A

Rama Rao, A. V. ; Singh, Ashok K. ; Rao, Batchu Venkateswara ; Reddy, Komandla Malla (1993) Synthesis of (±) Fredericamycin A Tetrahedron Letters, 34 (16). pp. 2665-2668. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)77651-9

Abstract

The synthesis of Fredericamycin A (1) has been achieved by subjecting the 1,3-dione (14) to an unusual 5-trigonal radical cyclization followed by reductive elimination of the halogen in 15 and subsequent demethylation.

Item Type:Article
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ID Code:38834
Deposited On:05 May 2011 05:47
Last Modified:05 May 2011 05:47

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