Rama Rao, A. V. ; Bhanu, Manjunath N. ; Sharma, G. V. M. (1993) Studies directed towards the total synthesis of rhizoxin: stereoselective synthesis of C-12 to C-18 segment Tetrahedron Letters, 34 (4). pp. 707-710. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)61659-3
Abstract
Chiral carbinol 5, made by a titanocene mediated ring opening of epoxy alcohol 11, was converted via an intramolecular radical cyclisation into a 'butanolide template' which was then transformed to the C-12 to C-18 segment 2 of rhizoxin 1). Synthesis of C-12 to C-18 segment of Rhizoxin is described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Butanolide Chiral Template; Chiral Carbinol; Intramolecular Radical Cyclisation; Vinyl Grignard Reaction |
| ID Code: | 38833 |
| Deposited On: | 05 May 2011 05:46 |
| Last Modified: | 05 May 2011 05:46 |
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