Nucleophilic addition of triethyl phosphite to acetates of the Baylis-Hillman adducts: stereoselective synthesis of (E)- and (Z)-allylphosphonates

Basavaiah, Deevi ; Pandiaraju, Subramanian (1996) Nucleophilic addition of triethyl phosphite to acetates of the Baylis-Hillman adducts: stereoselective synthesis of (E)- and (Z)-allylphosphonates Tetrahedron, 52 (6). pp. 2261-2268. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...

Related URL: http://dx.doi.org/10.1016/0040-4020(95)01055-6

Abstract

Nucleophilic addition of triethyl phosphite to 3-acetoxy-2-methylenealkanenitriles and methyl 3-acetoxy-2-methylenealkanoates provides (2E)-2-(diethoxyphosphorylmethyl)alk-2- enenitriles and methyl (2Z)-2-(diethoxy-phosphorylmethyl)alk-2-enoates respectively with good stereoselectivity.

Item Type:Article
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