The T3(π, π) state of acridine

Periasamy, N. (1983) The T3(π, π) state of acridine Chemical Physics Letters, 99 (4). pp. 322-325. ISSN 0009-2614

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The 0---0 band maximum of the transition T3(π, π)←T1 (π, π) of acridine occurs at ≈10200±20 cm-1 in inert (n-hexane, benzene, CCl4), at 10220±20 cm-1 in polar (acetonitrile) and at 10170±50 cm-1 in hydrogen-bonding (methanol, 2-propanol and alkaline water) solvents. Based on the solvent-independent energy of T1 (π, π), the T3(π, π) state of acridine is estimated at 26050±50 cm-1 in all the solvents.

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