Photoreduction of anthraquinone in aqueous micellar solution

Swayambunathan, V. ; Periasamy, N. (1980) Photoreduction of anthraquinone in aqueous micellar solution Journal of Photochemistry, 13 (4). 325-334 . ISSN 0047-2670

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Anthraquinol and surfactant-anthrahydroquinone ether are the major products of the UV photolysis of anthraquinone (AQ) in aqueous sodium dodecyl sulphate solution. Photoreduction of the triplet state of AQ by the surfactant alkyl chain is followed by a radical pair reaction which is either recombination or hydrogen abstraction. The photochemistry of AQ in micellar solution is compared with the results of the steady state photolysis and the laser photolysis of AQ in n-dodecane and other non-aqueous solvents.

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ID Code:37989
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