Polarography of uranium in thiocyanate medium

Saraiya, S. C. ; Srinivasan, V. S. ; Sundaram, A. K. (1960) Polarography of uranium in thiocyanate medium Analytica Chimica Acta, 23 . pp. 77-82. ISSN 0003-2670

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00032...

Related URL: http://dx.doi.org/10.1016/S0003-2670(60)80017-7


Uranyl ion in the presence of thiocyanate gave two polarographic waves, the first corresponding to a two-electron reduction of UO2+2 to U+4 and the second corresponding to a one-electron reduction of U+4 to U+3. The dependence of the two waves on acid concentration, temperature, etc., was studied.

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