Polarography of bismuth in oxalate and thiourea media

Sundaresan, R. ; Sundaram, A. K. (1973) Polarography of bismuth in oxalate and thiourea media Proceedings of the Indian Academy of Sciences, Section A, 78 (5). pp. 225-230. ISSN 0370-0089

PDF - Publisher Version

Official URL: http://www.ias.ac.in/j_archive/proca/78/5/225-230/...

Related URL: http://dx.doi.org/10.1007/BF03048090


The polarography of bismuth in the presence of thiourea and oxalate is discussed. Measurements could not be made in thiourea medium due to the dissolution of mercury. The reduction was irreversible in oxalate medium and the kinetic parameters as well as the stability constant of the predominant species were calculated from the formal potentials measured by amalgam polarography. The mixed complexes were not formed and the reduction was quasi-reversible in the presence of both the ligands.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
ID Code:37722
Deposited On:21 Apr 2011 07:28
Last Modified:17 May 2016 20:36

Repository Staff Only: item control page