Electrode kinetics of Eu3+/Eu2+ reaction by cyclic voltammetry

Radhakrishnan, T. P. ; Sundaram, A. K. (1980) Electrode kinetics of Eu3+/Eu2+ reaction by cyclic voltammetry Proceedings of the Indian Academy of Sciences - Chemical Sciences, 89 (4). pp. 381-385. ISSN 0253-4134

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Official URL: http://www.ias.ac.in/j_archive/chemsci/89/1/381-38...

Related URL: http://dx.doi.org/10.1007/BF02841410

Abstract

The cyclic voltammetric behaviour of Eu3+/Eu2+ couple at hanging mercury drop electrode (HMDE) has been studied in chloride, bromide, iodide, thiocyanate and EDTA supporting electrolytes. The apparent rate constant and transfer coefficient for these systems have been calculated at various voltage scan rates, without using the data for standard or formal potential. The values have been compared with those obtained by earlier workers through other electrochemical methods.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Cyclic Voltammetry; Rate Constant; Europium; Halides; Thiocyanate; EDTA
ID Code:37511
Deposited On:21 Apr 2011 07:32
Last Modified:17 May 2016 20:25

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