Polarography of europium(III) in water-dimethylformamide mixtures

Chandrasekaran, V. R. ; Sundaram, A. K. (1981) Polarography of europium(III) in water-dimethylformamide mixtures Proceedings of the Indian Academy of Sciences - Chemical Sciences, 90 (4). pp. 275-280. ISSN 0253-4134

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Official URL: http://www.ias.ac.in/j_archive/chemsci/90/3/275-28...

Related URL: http://dx.doi.org/10.1007/BF02879400


The kinetics of the electrochemical reduction of europium(III) in water-N, N dimethyl formamide mixtures in potassium chloride medium has been studied. The formal rate constant for the reduction increases markedly from 10-4 cm sec-1 in low concentrations to 10-2 cm sec-1 at high concentrations of the solvent. The effects of solvent on the formal potential and diffusion current are discussed.

Item Type:Article
Source:Copyright of this article belongs to Indian Academy of Sciences.
Keywords:Polarography; Europium; Dimethylformamide
ID Code:37498
Deposited On:21 Apr 2011 07:32
Last Modified:17 May 2016 20:24

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