Bhuvaneswaria, N. ; Balasubramanian, K. K. ; Venkatachalam, C. S. (1993) Proton-transfer reactions in the cathodic reduction of bromohydrins in neutral aprotic media Journal of Electroanalytical Chemistry, 354 (1-2). pp. 223-230. ISSN 0022-0728
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002207...
Related URL: http://dx.doi.org/10.1016/0022-0728(93)80335-F
Abstract
Polarographic and cyclic voltammetric studies of bromohydrins in acetonitrile showed a single diffusion-limited two-electron irreversible cathodic wave/peak followed by chemical transformations. Controlled-potential electrolyses of the compounds gave a mixture of two products with epoxide as one of them in all cases. The mechanism of reduction is discussed in the light of proton-transfer reactions in neutral aprotic media.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 3748 |
| Deposited On: | 18 Oct 2010 09:52 |
| Last Modified: | 13 May 2011 07:01 |
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