Control of coherence length and aggregate size in the J-aggregate of porphyrin

Koti, A. S. R. ; Taneja, Jharna ; Periasamy, N. (2003) Control of coherence length and aggregate size in the J-aggregate of porphyrin Chemical Physics Letters, 375 (1-2). pp. 171-176. ISSN 0009-2614

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00092...

Related URL: http://dx.doi.org/10.1016/S0009-2614(03)00866-2

Abstract

The spectroscopic aggregation number (coherence length) and physical size of the J-aggregates of anionic meso-tetrakis(4-sulphonatophenyl)porphyrin (H4TPPS2-) are controlled by ammonium ion concentration. The contributions of absorption and scattering are determined using the extinction and resonance light scattering (RLS) spectra of the TPPS J-aggregate. The highest spectroscopic aggregation number (12.9) was determined for the J-aggregate of hydrodynamic radius of 56±10 nm.

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ID Code:37341
Deposited On:22 Apr 2011 12:34
Last Modified:17 May 2016 20:15

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