Studies on efficiencies of electrochemiluminescence of rubrene

Periasamy, N. ; Santhanam, K. S. V. (1974) Studies on efficiencies of electrochemiluminescence of rubrene Proceedings of the Indian Academy of Sciences, Section A, 80 (4). pp. 194-206. ISSN 0370-0089

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The electrochemiluminescence efficiencies of rubrene system has been obtained by using the transient method in a variety of solvents. The efficiencies are in the range of 0·11×10-3-4·1×10-2. The mixed system efficiencies are less at least by an order of magnitude in all the solvents except in dimethylsulphoxide. The variation in efficiencies of the pure and mixed systems is explained on the basis of mechanistic differences. In the applied magnetic field, the electrochemiluminescence efficiency of the pure system increases by about 7% and of the mixed system by about 18-25%.

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