A simple, direct synthesis of Na2Fe(CO)4

Devasagayaraj, Arockiasamy ; Periasamy, Mariappan (1991) A simple, direct synthesis of Na2Fe(CO)4 Transition Metal Chemistry , 16 (5). pp. 503-504. ISSN 0340-4285

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Official URL: http://www.springerlink.com/content/r6778168156n75...

Related URL: http://dx.doi.org/10.1007/BF01024317


Reduction of anhydrous FeCl3 in THF with sodium naphthalenide under a CO atmosphere at room temperature leads directly to Na2Fe(CO)4, which on reaction with alkyl bromides gives the corresponding aldehydes, ketones and carboxylic acids under appropriate conditions.

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