Sanjeevakumar, Nalluri ; Periasamy, Mariappan (2009) Highly enantioselective Henry reaction catalyzed by a new chiral C2-symmetric N,N'-bis(isobornyl)ethylenediamine–copper complex Tetrahedron: Asymmetry, 20 (16). 1842-1847 . ISSN 0957-4166
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09574...
Related URL: http://dx.doi.org/10.1016/j.tetasy.2009.07.040
Abstract
A new chiral C2-symmetric N,N'-bis(isobornyl)ethylenediamine–copper complex is found to be an efficient catalyst in the enantioselective Henry reaction between nitromethane and various aldehydes to provide β-hydroxy nitroalkanes with high chemical yield (up to 95%) and high enantiomeric excess (up to 90%).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 37287 |
| Deposited On: | 25 Apr 2011 08:10 |
| Last Modified: | 05 May 2011 03:46 |
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