A simple TiCl4 promoted arylation of orthoformate and benzyl ethers by N,N-dialkylarylamines

Periasamy, Mariappan ; Kishorebabu, Neela ; Natarajan Jayakumara, K. (2007) A simple TiCl4 promoted arylation of orthoformate and benzyl ethers by N,N-dialkylarylamines Tetrahedron, 48 (11). pp. 1955-1958. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.01.079

Abstract

N,N-Dialkylarylamines react with trimethyl orthoformate and TiCl4 under ambient conditions to give the corresponding formyl derivatives in 75–89% yields, whereas the corresponding arylated products are obtained from benzyl ethers and acetals in 42–78% yields.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:N,N-Dialkylarylamines; Trimethyl Orthoformate; Formylation; Titanium Tetrachloride
ID Code:37192
Deposited On:25 Apr 2011 08:08
Last Modified:25 Apr 2011 08:08

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