Lakshmi Narayana Rao, M. ; Periasamy, Mariappan (1998) The CoCl2/Ph(Et)2N:BH3/CO system: reactions of the borane and cobalt carbonyl species Journal of Organometallic Chemistry, 553 (1-2). pp. 91-97. ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...
Related URL: http://dx.doi.org/10.1016/S0022-328X(97)00596-2
Abstract
The CoCl2/Ph(Et)2N:BH3/CO system is useful for the hydroboration and carbonylation of alkenes to obtain the corresponding dialkyl ketones. The cobalt carbonyl species formed in situ in this way is also useful for hydroacylation–cyclisation of norbornene and for the Pauson–Khand reaction.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Hydroboration; Alkene; Carbonylation; Dialkylketone; Cobalt Carbonyl Reagents; Carbonylative Cyclisations |
| ID Code: | 37163 |
| Deposited On: | 25 Apr 2011 08:05 |
| Last Modified: | 25 Apr 2011 08:05 |
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