Periasamy, Mariappan ; Bhanu Prasad, A. S. ; Suseela, Yantrapragada (1995) Synthesis of Z-alkenes from alkenylcatecholboranes through reaction with RMgX and I2 induced rearrangement Tetrahedron, 51 (9). 2743-2748 . ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004040...
Related URL: http://dx.doi.org/10.1016/0040-4020(95)00023-2
Abstract
Addition of RMgX and BrMg (CH2) nMgBr reagents to alkenylcatecholborane followed by iodine induced rearrangement and oxidation provided Z-olefins and Z-olefinic alcohols in moderate to good yields. This procedure is advantageous over the previous methods of synthesis of Z-olefins from alkenylboranes since the alkyl groups which are not available through hydroborations can be also utilized.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 37152 |
| Deposited On: | 25 Apr 2011 08:04 |
| Last Modified: | 25 Apr 2011 08:04 |
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