A novel arylation of arylacetic acid esters using tertiary arylamines and TiCl4

Periasamy, Mariappan ; Kishore Babu, N. ; Natarajan Jayakumar, Keela (2003) A novel arylation of arylacetic acid esters using tertiary arylamines and TiCl4 Tetrahedron Letters, 44 (50). 8939-8941 . ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2003.10.009

Abstract

The reactions of arylacetic acid esters with tertiary arylamines in the presence of TiCl4 give α-arylated products in 65–90% yields, as well as 10–20% yields of the corresponding benzidines.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Diaryl Acetic Esters; Cross Coupling Reactions; Titanium Enolates; Aryltitanium
ID Code:37151
Deposited On:25 Apr 2011 08:07
Last Modified:25 Apr 2011 08:07

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