The synthesis of novel chiral macrocyclic and polymeric amines containing a trans-1,2-diaminocyclohexane system

Padmaja, Meduri ; Periasamy, Mariappan (2004) The synthesis of novel chiral macrocyclic and polymeric amines containing a trans-1,2-diaminocyclohexane system Tetrahedron: Asymmetry, 15 (15). 2437-2441 . ISSN 0957-4166

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09574...

Related URL: http://dx.doi.org/10.1016/j.tetasy.2004.07.005

Abstract

The reactions of (R,R)-N,N'-diisopropyl-1,2-diaminocyclohexane with isomeric benzylic dibromides gave heterocycles and macrocycles. Additionally a reaction with adipoyl chloride gave a polymeric amido carboxylic acid that could be readily reduced to the corresponding polyamino alcohol using the NaBH4/I2 reagent system.

Item Type:Article
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ID Code:37139
Deposited On:25 Apr 2011 08:07
Last Modified:25 Apr 2011 08:07

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